Well I incorrectly assumed that this was some flavor of a SPUser object, turns out the person field in a SPList is a special type SPFieldUser.
Well lets cut to the chase this is the code to access the email address of a SPListItem person column;
private bool EmailUser(SPListItem spListItem, string recordColumn, string subject, string message)
{
SPFieldUser spFieldUser = (SPFieldUser)spListItem.Fields[recordColumn];
SPFieldUserValue spFieldUserValue = (SPFieldUserValue)spFieldUser.GetFieldValue(
spListItem[recordColumn].ToString());
if (string.IsNullOrEmpty(spFieldUserValue.User.Email) == false)
return SPUtility.SendEmail(spListItem.Web, false, false, spFieldUserValue.User.Email, subject, message);
else
LogWrite("Error", string.Format("Send Email Error Message")
,spFieldUserValue.User.Name));
return false;
}